安徽黄梅尖地区基性岩脉K-Ar年代学、地球化学特征及地质意义          下载免费PDF全文

杨彪  王正其  肖金根  曹达旺 《华东地质》2020,(1):27-35

在野外地质调查和室内综合研究的基础上,通过对黄梅尖地区辉绿玢岩K-Ar年代学、地球化学和Sr-Nd同位素特征进行研究,探讨辉绿玢岩的形成时代、岩石成因及构造背景。K-Ar年代学研究表明,辉绿玢岩形成于~107 Ma,是早白垩世岩浆活动的产物,形成时代晚于该地区火山岩和侵入岩,与该地区铀成矿年龄基本一致;辉绿玢岩的侵入可能是该地区岩浆作用的最后一幕,铀成矿可能与辉绿玢岩具有成因联系。地球化学特征表明,辉绿玢岩富集大离子亲石元素K、Rb、U、Pb和轻稀土元素,亏损高场强元素Nb、Ta、P、Ti,具有较高的Isr值和负εNd(t)值,具有富集地幔源区特征;辉绿玢岩是在地壳伸展和岩石圈减薄的构造背景下,由俯冲交代作用形成的富集地幔部分熔融形成的,表明~107 Ma时该地区仍处于伸展构造环境下。  相似文献   

Cu–Mo Differential Mineralization Mechanism of the Dabate Polymetallic Deposit in Western Tianshan,NW China: Evidence from Geology,Fluid Inclusions,and Oxygen Isotope Systematics     

Rui Cao  Shengchao Yan  Bin Chen  Keke Sun  Qinglin Zhang  Haodong Gu 《Resource Geology》2020,70(1):50-69

Classic porphyry Cu–Mo deposits are mostly characterized by close temporal and spatial relationships between Cu and Mo mineralization. The northern Dabate Cu–Mo deposit is a newly discovered porphyry Cu–Mo polymetallic deposit in western Tianshan, northwest China. The Cu mineralization postdates the Mo mineralization and is located in shallower levels in the deposit, which is different from most classic porphyry Cu–Mo deposits. Detailed field investigations, together with microthermometry, laser Raman spectroscopy, and O‐isotope studies of fluid inclusions, were conducted to investigate the origin and evolution of ore‐forming fluids from the main Mo to main Cu stage of mineralization in the deposit. The results show that the ore‐forming fluids of the main Mo stage belonged to an NaCl + H₂O system of medium to high temperatures (280–310°C) and low salinities (2–4 wt% NaCl equivalent (eq.)), whereas that of the main Cu stage belonged to an F‐rich NaCl + CO₂ + H₂O system of medium to high temperatures (230–260°C) and medium to low salinities (4–10 wt% NaCl eq.). The δ¹⁸O values of the ore‐forming fluids decrease from 3.7–7.8‰ in the main Mo stage to ?7.5 to ?2.9‰ in the main Cu stage. These data indicate that the separation of Cu and Mo was closely related to a large‐scale vapor–brine separation of the early ore‐forming fluids, which produced the Mo‐bearing and Cu‐bearing fluids. Subsequently, the relatively reducing (CH₄‐rich) Mo‐bearing, ore‐forming fluids, dominantly of magmatic origin, caused mineralization in the rhyolite porphyry due to fluid boiling, whereas the relatively oxidizing (CO₂‐rich) Cu‐bearing, ore‐forming fluids mixed with meteoric water and precipitated chalcopyrite within the crushed zone at the contact between rhyolite porphyry and wall rock. We suggest that the separation of Cu and Mo in the deposit may be attributed to differences in the chemical properties of Cu and Mo, large‐scale vapor–brine separation of early ore‐forming fluids, and changes in oxygen fugacity.  相似文献   

甘肃柳园地区早二叠世正长花岗斑岩脉锆石U-Pb年代学、岩石地球化学特征——对北山造山带晚古生代构造背景的指示     

孙海瑞  吕志成  于晓飞  李永胜  杜泽忠  吕鑫  公凡影 《吉林大学学报(地球科学版)》2020,50(5):1433-1449

甘肃北山地区位于中亚造山带中段，是诠释中亚造山带构造演化的关键区域之一，长期以来受到地质学界的广泛关注。柳园地区位于甘肃北山南带，区内脉岩发育，这些岩脉的研究可以为阐释北山造山带晚古生代构造背景提供更多证据。基于此，本文选取位于甘肃柳园地区的正长花岗斑岩脉开展了系统的锆石U-Pb-Hf同位素和全岩主量、微量元素分析。LA-ICP-MS锆石U-Pb分析显示，岩脉侵位于早二叠世（（288.5±1.4）Ma）。全岩地球化学分析显示，正长花岗斑岩脉的SiO₂和全碱质量分数较高，Fe、Mg、Ca、Al和P质量分数较低，Rb、Th、U和Pb相对富集，Ba、Nb、La、Ce、Sr和Ti等元素相对亏损，Eu负异常显著，具有较高的Rb/Sr值和较低的K/Rb值及锆石饱和温度（730~844℃，集中于740℃左右），显示该岩脉为高钾钙碱性高分异I型花岗岩，并具有俯冲带岩浆活动的地球化学特征。正长花岗斑岩脉具有较低的Zr/Hf值（18.42~28.01，平均值为22.37）和Th/U值（3.82~7.99，平均值为5.34），与平均地壳组分接近，锆石ε_Hf（t）值为2.94~9.66，平均值为5.72，T_DM2值为955~611 Ma，指示源区主体为新元古代地壳的部分熔融，并存在幔源物质加入。根据构造判别图解并结合前人关于二叠纪区域构造变形、盆地沉积物源、岩浆演化等方面的研究结果，笔者认为该正长花岗斑岩脉形成于俯冲作用过程中的局部伸展环境，并认为北山地区增生造山事件至少持续到早二叠世。  相似文献   

冲绳海槽中部岩心沉积物中浮岩的物理性质和地球化学特征差异及其对岩浆活动的指示     

方雪  曾志刚  胡思谊  朱博文  齐海燕  万世明  徐兆凯 《海洋科学》2020,44(5):1-11

为进一步了解冲绳海槽浮岩的物理性质和地球化学特征差异,对冲绳海槽中部岩心沉积物S9中的浮岩进行了微观结构和地球化学组成分析。结果显示,冲绳海槽中部存在白色、灰白色及棕色3种浮岩,其中灰白色浮岩又可以根据构造特征分为气孔构造和流动构造浮岩两个亚类。浮岩的地球化学组成表明白色、灰白色及棕色浮岩都是由玄武质岩浆经过充分的分离结晶作用形成的流纹质或流纹英安质火山岩。玄武质岩浆在演化的过程中发生了斜长石、角闪石、辉石、Fe-Ti氧化物、磷灰石等矿物的结晶分离。结合有孔虫14C年龄,认为浮岩是冲绳海槽中部距今13.1 ka左右的长英质火山活动的产物。演化程度相对较低的棕色浮岩具有比白色浮岩高的TiO2, Al2O3, Fe2O3, MgO, CaO含量,且棕色浮岩具有相对低的稀土总量和轻稀土总量。根据浮岩的物理性质及地球化学组成差异推测,岩浆的黏度和压力是影响浮岩构造特征的主要因素。黏度大、连续减压的岩浆易于形成具有流动构造和密集气孔的浮岩,黏度小、阶段性减压的岩浆易于形成气孔大而疏松的浮岩。  相似文献   

致密砂岩层内强钙质胶结物成因机制及其意义——以鄂尔多斯盆地三叠系延长组长7油层组为例     

崔景伟  朱如凯 《吉林大学学报(地球科学版)》2020,50(4):957-967

通过岩心和薄片观察，利用荧光显微镜、阴极发光显微镜、同位素质谱仪、冷热台等设备，对鄂尔多斯盆地长7油层组强钙质胶结砂岩及其附近含油砂岩开展研究。结果表明：钙质胶结是致密砂岩储层含油非均质性的主要因素，胶结期次主要为一期；簇同位素揭示该期钙质胶结物的形成温度为18~42℃，对应地质时代为中晚三叠世—中侏罗世，为早成岩期产物，推测与盆地早期小规模构造运动相关；相邻的含油砂岩中油气包裹体伴生的同期盐水包裹体的均一化温度为90~120℃，结合盆地模拟揭示油气主要为一期充注，充注期为100~130 Ma，处于早白垩世；长7油层组不含油致密砂岩内钙质胶结物形成时间早于含油砂岩内石油的充注时间。  相似文献   

Episodic crustal growth in the Tanzania Craton: evidence from Nd isotope compositions     

《China Geology》2018,1(2):210-224

The analysis of available Nd isotope data from the Tanzania Craton places important constraints on the crust-mantle separation ages, and events marking juvenile crustal addition and crustal recycling. Nd model ages date the oldest crust extraction to 3.16 Ga in the Tanzania Craton, although a rock record of such antiquity is yet to be found there. The most significant period of juvenile crustal addition as well as crustal recycling is 2.7–2.6 Ga. The Nd isotopes of mafic samples show that chemical heterogeneity existed in the mantle beneath the Tanzania Craton, with some samples originating from significantly depleted mantle, and most samples originating from the mixture of primitive mantle and depleted mantle. The Nd isotope section reveals significant differences in Nd isotopes between the north craton and central craton; compared to the north craton, the central craton yields a Nd model age that is approximately 100 Ma older, and its ε_Nd(t) values are more negative, indicating that the two parts of the craton have different mantle source regions. Different types of granitoids are distributed in the Tanzania Craton, such as high-K and low-Al granite, calc-alkaline granite, peraluminous granite and transitional types of tonalite-trondhjemite-granodiorites (TTGs). Most of the granitoids formed later than the mafic rocks in syn-collision and post-collision events.  相似文献   

滇西芦子园远程矽卡岩Pb-Zn-Fe(Cu)多金属矿床流体包裹体初探及矿床成因探讨   总被引：4，自引：4，他引：0  

邓明国  陈伟  王学武  刘凤祥  管申进  卢映祥  余海军  赵发 《岩石学报》2018,34(5):1239-1257

滇西镇康芦子园是"三江"成矿带保山地块内迄今发现的唯一超大型Pb-Zn-Fe(Cu)多金属矿床,是区内系列同类层控热液铅锌矿床的典型代表。矿体呈似层状、脉状及透镜状产于寒武系碳酸盐岩建造的矽卡岩和大理岩层间破碎带,矿石构造以条带状、浸染状和脉状-网脉状为主要特征;围岩蚀变复杂、分带明显,由下至上依次为石榴子石-透辉石-透闪石-阳起石化带→绿泥石-绿帘石-阳起石-蔷薇辉石化带→碳酸盐-大理岩化带。矿床成矿流体从早期到晚期经历了多个矿化阶段。本文选取了该矿床早矽卡岩阶段、晚矽卡岩阶段、石英硫化物阶段和石英碳酸盐阶段的多种脉石矿物及闪锌矿进行了系统的流体包裹体研究。结果显示,早矽卡岩阶段发育微溶CO_2富液相和纯液相水溶液包裹体,并含大量K~+、Na~+、Ca~(2+)、F~-和Cl~-和少量SO_4~(2-),气相成分主要为H_2O、CO_2及少量CH_4和N_2,包裹体均一温度为233.6~315.6℃,盐度为10.6%~17.6%NaCleqv;晚矽卡岩阶段发育含CO_2和子矿物三相包裹体,均一温度214.9~388.0℃,盐度5.9%~16.4%NaCleqv;石英硫化物阶段发育含CO_2的水溶液包裹体,气相成分为CH_4、H_2O和少量CO_2,均一温度150.0~285.0℃,盐度为2.5%~13.8%NaCleqv;石英碳酸盐阶段为单一成分的水溶液包裹体,均一温度为105.0~187.5℃,盐度为0.5%~12.3%NaCleqv。结合H-O同位素研究表明,成矿流体最初来源于具中高温、中高盐度、高K、Na,富CO_2、Cl、F等特征的深部岩浆热液,在石英硫化物阶段开始有大气降水混入,演化为中阶段中低温、低盐度、贫CO_2的热液流体,至成矿晚阶段转化为以大气降水占主导。该矿床成矿环境的改变、流体混合以及流体的沸腾作用可能是导致成矿物质富集沉淀的重要机制。综合矿床地质特征、成矿流体包裹体和HO同位素研究认为,该矿床为与陆陆碰撞造山和深部隐伏岩体有关的远程矽卡岩成矿系统。  相似文献   

长白山火山下方地幔转换带中滞留的俯冲太平洋板块存在空缺吗?   总被引：5，自引：3，他引：2  

雷建设  赵大鹏  徐义刚  樊祺诚  米琦  杜沫霏  鲁明文 《岩石学报》2018,34(1):13-22

针对近年来长白山火山下方地幔转换带中是否存在低波速异常指示的太平洋板块"空缺"而引起的不同科学认识的热烈辩论,本文主要回顾了我国东北地区地幔转换带的体波成像结果。使用相对走时残差的远震体波成像结果显示,长白山火山以西地幔转换带中存在低波速异常指示的太平洋板块"空缺";而使用绝对走时残差的区域成像和全球成像结果,尽管展示出长白山火山以西比以东略低的波速异常,但长白山火山以东至我国东北重力梯度带区域下方的地幔转换带均展示出明显的连续的高波速异常。在接收函数分析时,如果以全球平均值660km而非我国东北地区平均值670km作为基准,来分析660km间断面是抬升还是下沉;以全球平均值250km而非我国东北地区平均值260km作为基准,来分析地幔转换带是增厚还是减薄的话,则可以得到长白山火山以东至我国东北重力梯度带区域660km间断面下沉与地幔转换带增厚的认识。这种与绝对走时残差成像结果展示的地幔转换带为连续的高波速异常结果相一致的结果,说明太平洋板块俯冲前缘已由日本海沟抵达我国东北松辽盆地与大兴安岭交界处。结合高温高压实验、数值模拟与岩石地球化学研究结果,本文并不支持长白山火山以西的地幔转换带存在低波速异常指示的板块"空缺"和地幔转换带"减薄"的认识。长白山火山的深部起源与太平洋板块深俯冲至我国东北松辽盆地与大兴安岭交界处形成的"大地幔楔"结构动力学相关。  相似文献   

藏南喜马拉雅造山带造山型马扎拉Au-Sb矿床和沙拉岗Sb矿床流体包裹体He-Ar同位素组成:对成矿流体来源的制约   总被引：2，自引：1，他引：1  

翟伟  郑思琦  孙晓明  韦慧晓  莫儒伟  张凌宇  周峰  易建洲 《岩石学报》2018,34(12):3525-3538

马扎拉Au-Sb矿床和沙拉岗Sb矿床是藏南金锑成矿带中典型的造山型矿床。马扎拉Au-Sb矿床中矿体以含金辉锑矿石英脉的形式产于下中侏罗统陆热组地层中,主要组成矿物有自然金、辉锑矿、石英和碳酸盐矿物;沙拉岗Sb矿床中矿体主要以辉锑矿石英脉的形式产于下白垩统多久组地层和辉长岩体中,主要组成矿物为辉锑矿、辰砂、锑华、石英和少量碳酸盐矿物。在两个矿床的矿脉石英和辉锑矿中均发现有三类原生和假次生包裹体:水溶液包裹体、CO2-水溶液包裹体和有机包裹体。流体包裹体显微测温结果显示:马扎拉Au-Sb矿床的成矿温度为160～280℃,沙拉岗Sb矿床的成矿温度为140～240℃。He-Ar同位素分析显示马扎拉Au-Sb矿辉锑矿石英脉矿石中辉锑矿和石英以及赋矿地层中沉积层状硫化物中黄铁矿的流体包裹体均具有低的3He/4He比值,分别为0. 01382～0. 05642Ra和0. 03353～0. 08744Ra,40Ar/36Ar比值具有比较大的变化范围,分别为346. 8～4770. 1和349. 4～2689. 1;沙拉岗Sb矿床中辉锑矿样品的3He/4He比值为0. 02385～0. 11488Ra,40Ar/36Ar比值变化小,为300. 6～537. 5。与藏南Au-Sb成矿带中造山型Au矿床成矿流体中含一定量的幔源挥发份相对比,马扎拉AuSb矿床和沙拉岗Sb矿床成矿流体中均无幔源流体的参与,马扎拉Au-Sb矿床成矿流体为壳源变质流体与改造型饱和大气水形成的混合流体;沙拉岗Sb矿床成矿流体以改造型饱和大气水为主,并有壳源变质流体的加入。  相似文献   

Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions     

WU Yingzhong  DUAN Yi  ZHAO Yang  CAO Xixi  MA Lanhu  QIAN Yaorong  LI Zhongping  XING Lantian 《《地质学报》英文版》2018,92(5):1879-1887

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values (Ro) of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ13C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.  相似文献